[Ge9{Si(SiMe3)3}3{SnPh3}]: a tetrasubstituted and neutral deltahedral nine-atom cluster.

Angew Chem Int Ed Engl

Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.

Published: August 2012

Reaching neutral territory: The title compound, the first tetrasubstituted deltahedral Zintl cluster, is no longer an ion (see picture; Ge green, Si purple, Sn blue). It is a neutral molecule formed by a reaction of the trisilylated anion with Ph(3) SnCl.

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http://dx.doi.org/10.1002/anie.201202906DOI Listing

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