Hierarchical self-assembly of polycyclic heteroaromatic stars into snowflake patterns.

Angew Chem Int Ed Engl

Kekulé-Institut für Organische Chemie und Biochemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn, Germany.

Published: August 2012

Seeing stars: The two-dimensional patterns of the polycyclic heteroaromatic star molecules 1 on graphite vary with the side chain length. For n=12, frustrated self-assembly leads to hierarchically organized superstructures: up to 10 molecules form triangular aggregates which pack densely into hexagonal patterns with very large (15.5 nm) lattice constants.

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Source
http://dx.doi.org/10.1002/anie.201204006DOI Listing

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