In the ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the mean planes of the benzene ring and the substituted cyclo-penta-dienyl ring is 84.63 (7)°. The conformation of the title compound significantly differs from those found in corresponding m-tolyl-amino and p-tolyl-amino derivatives. In the crystal, C-H⋯O inter-actions connect the mol-ecules into chains, which further inter-act by means of C-H⋯π inter-actions. It is noteworthy that the amino H atom is shielded and is not involved in hydrogen bonding.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393239 | PMC |
| http://dx.doi.org/10.1107/S1600536812028802 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Article Synopsis
- Nanocatalytic medicine aims to improve cancer treatment by developing nanotechnologies that selectively target tumor cells while sparing normal cells.
- The proposed solution involves using pH- and redox-responsive ferrocene-containing polymersomes (FcPsomes) that can control radical production and release therapeutic molecules based on their environment.
- These FcPsomes can facilitate a synergistic treatment approach by producing reactive oxygen species through the Fenton reaction, allowing for targeted and safe therapies that adapt to the tumor's conditions.
Ferrocene-Modified Polyacrylonitrile-Containing Block Copolymers as Preceramic Materials.
Polymers (Basel)
July 2024
Polymer Chemistry, Campus C4 2, Saarland University, 66123 Saarbrücken, Germany.
In the pursuit of fabricating functional ceramic nanostructures, the design of preceramic functional polymers has garnered significant interest. With their easily adaptable chemical composition, molecular structure, and processing versatility, these polymers hold immense potential in this field. Our study succeeded in focusing on synthesizing ferrocene-containing block copolymers (BCPs) based on polyacrylonitrile (PAN).
View Article and Find Full Text PDFSyntheses, Characterization, and Redox Activity of Ferrocene-Containing Titanium Complexes.
ACS Omega
July 2024
Institut für Chemie, Carl von Ossietzky Universität Oldenburg, D-26111 Oldenburg, Federal Republic of Germany.
The chemistry of bis(π-η:σ-η-pentafulvene)titanium complexes is characterized by a broad range of E-H activation and Ti-C functionalization reactions, whereas ferrocene derivatives are easily accessible and redox-active compounds. The reaction of ferrocenealdehyde and -ketones with bis(π-η:σ-η-pentafulvene)titanium complexes result in the formation of bimetallic complexes via insertion of the C=O double bond of the aldehyde/ketone into the Ti-C bond of the pentafulvene moiety. The reaction of bis(π-η:σ-η-pentafulvene)titanium complexes with ferrocenyl alcohols leads to alcoholate complexes via deprotonation of the OH group by the pentafulvene ligand.
View Article and Find Full Text PDFElectroactive Behavior of Adjustable Vinylferrocene Copolymers in Electrolyte Media.
J Phys Chem B
February 2024
Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.
The redox-active properties of a series of ferrocene-containing vinyl polymers were investigated in aqueous and organic media. Each metallopolymer contained vinylferrocene (VFc) and a non-redox-active species (X), and was combined with carbon nanotubes (CNT) to generate P(VFc--X)-CNT composites for heterogeneous electrochemical analysis. Tunable pseudocapacitances spanning ca.
View Article and Find Full Text PDFRegio- and Stereoselective Iodoamination of Ferrocene-Containing Allenylphosphonates: Synthesis of Multifunctional Tetrasubstituted Allylic Amines and Allylic Azides.
J Org Chem
February 2024
Department of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, People's Republic of China.
A general and practical methodology for the regio- and stereoselective synthesis of multifunctional tetrasubstituted allylic amines and azides based on iodoamination of ferrocene-containing allenylphosphonates with anilines and sodium azide is described. A tetrasubstituted olefin moiety, as well as an iodine atom, a phosphonate, and a ferrocene group, are installed to the allylic amine motif simultaneously in moderate to good yields.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!