In the title complex, [La(C₇H₄BrO₃)Cl₂(C₁₂H₈N₂)](n), the La(III) ion is eight-coordinated by two carboxyl-ate O atoms from two 5-bromo-salicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-anti-prismatic geometry. The La(III) ions are linked by bridging carboxyl-ate groups and chloride anions into a chain along [100]. An intra-molecular O-H⋯O hydrogen bond is formed in the 5-bromo-salicylate ligand. π-π inter-actions between the pyridine and benzene rings and between the benzene rings are observed [centroid-centroid distances = 3.794 (5) and 3.804 (4) Å].
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| http://dx.doi.org/10.1107/S1600536812025500 | DOI Listing |
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