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Poly[μ₂-aqua-μ₄-(2-{3-[(6-chloro-pyridin-3-yl)meth-yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]. | LitMetric

Poly[μ₂-aqua-μ₄-(2-{3-[(6-chloro-pyridin-3-yl)meth-yl]-2-oxoimidazolidin-1-yl}acetato)-sodium].

Acta Crystallogr Sect E Struct Rep Online

X-ray Crystallography Laboratory, Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi 180 006, India.

Published: July 2012

AI Article Synopsis

Article Abstract

In the title compound, [Na(C₁₁H₁₁ClN₃O₃)(H₂O)](n), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa-hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal-bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The Na(I) ions bridge organic ligands and water mol-ecules, forming a two-dimensional structure parallel to (100). There are inter-molecular O-H⋯O and weak C-H⋯O hydrogen bonds within the two-dimensional structure.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393166PMC
http://dx.doi.org/10.1107/S1600536812025007DOI Listing

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