Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III).

Acta Crystallogr Sect E Struct Rep Online

Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, People’s Republic of China.

Published: July 2012

In the title compound, [Cu(C₂₇H₂₆P₂)₂][GaCl₄], the Cu(I) atom in the complex cation is P,P'-chelated by two 1,3-bis-(diphenyl-phosphan-yl)propane ligands in a distorted tetra-hedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetra-hedral geometry. In the crystal, weak C-H⋯π inter-actions occur between adjacent complex cations.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393151PMC
http://dx.doi.org/10.1107/S1600536812024269DOI Listing

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