N-(4-Methyl-benz-yl)-3-nitro-anilinium chloride.

Acta Crystallogr Sect E Struct Rep Online

Published: July 2012

The cation of the title compound, C(14)H(15)N(2)O(2) (+)·Cl(-), comprises two almost ideally planar systems, 3-nitro-phenyl (r.m.s. deviation = 0.0117 Å) and 4-methyl-phenyl (r.m.s. deviation = 0.238 Å), separated by the central C-N bond, and with their mean planes inclined to one another by 61.36 (5)°. In the crystal, hydrogen-bonded chains running along [001] are generated by connecting neighbouring mol-ecules via N-H⋯Cl hydrogen bonds and consolidated by C-H⋯Cl and C-H⋯O inter-actions. Within these chains, fused R(2) (1)(6) and R(3) (2)(10) ring motifs are formed. Parallel chains are further linked into a two-dimensional network parallel to (100) via C-H⋯O inter-actions.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393960PMC
http://dx.doi.org/10.1107/S1600536812026281DOI Listing

Publication Analysis

Top Keywords

rms deviation
8
c-h⋯o inter-actions
8
n-4-methyl-benz-yl-3-nitro-anilinium chloride
4
chloride cation
4
cation title
4
title compound
4
compound c14h15n2o2
4
c14h15n2o2 +·cl-
4
+·cl- comprises
4
comprises ideally
4

Similar Publications

Clinical Relevance: Horizontal rectus muscle surgeries may cause changes in corneal and anterior segment parameters. Corneal topography is an important device for identifying these alterations.

Background: The aim of this work is to evaluate the effects of horizontal rectus muscle surgeries on corneal topography, anterior chamber parameters and corneal wavefront aberrations.

View Article and Find Full Text PDF

Aim And Background: Glass ionomer cement (GIC) serves as a widely used restorative dental material, known for its direct bonding to tooth structures and fluoride-releasing properties. This study aims to investigate the enhancement of GIC through the incorporation of a green-mediated nanocomposite comprising chitosan, titanium, zirconium, and hydroxyapatite, with a focus on evaluating the wear resistance of the modified GIC.

Materials And Methods: A one-pot synthesis technique was utilized to prepare a green-mediated nanocomposite incorporating chitosan, titanium, zirconium, and hydroxyapatite nanoparticles.

View Article and Find Full Text PDF

Background And Objectives: The present study aims to assess and compare the accuracy of post-space impressions captured by three different intraoral scanners (IOS) using various canal diameters.

Methods: Three extracted natural maxillary central incisors were selected and prepared for a 1 mm wide margin and a 3 mm ferrule. All steps required for the endodontic procedure were performed, and the post space was prepared using post drills.

View Article and Find Full Text PDF

Objectives: To evaluate the accuracy (trueness and precision) of liquid crystal display (LCD)-printed orthognathic surgical splints under two different post-processing conditions-rinsing solvent and post-polymerization time.

Materials And Methods: An LCD 3D printer was used to create 48 surgical splints using the same reference standard tessellation language (STL) files. They were randomly assigned to two experimental studies.

View Article and Find Full Text PDF

Objective: This study aimed to compare the manufacturing accuracy of different printing techniques - Stereolithography (SLA), Digital Light Processing (DLP), and PolyJet-using digital dental models.

Methods: The study included cast models of 30 patients aged between 12 and 20 years. The selected models were scanned using an intraoral scanner, and surface topography format files were obtained.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!