The electron-phonon interaction is of central importance for the electrical and thermal properties of solids, and its influence on superconductivity, colossal magnetoresistance and other many-body phenomena in correlated-electron materials is the subject of intense research at present. However, the non-local nature of the interactions between valence electrons and lattice ions, often compounded by a plethora of vibrational modes, presents formidable challenges for attempts to experimentally control and theoretically describe the physical properties of complex materials. Here we report a Raman scattering study of the lattice dynamics in superlattices of the high-temperature superconductor YBa(2)Cu(3)O(7) (YBCO) and the colossal-magnetoresistance compound La(2/3)Ca(1/3)MnO(3) that suggests a new approach to this problem. We find that a rotational mode of the MnO(6) octahedra in La(2/3)Ca(1/3)MnO(3) experiences pronounced superconductivity-induced line-shape anomalies, which scale linearly with the thickness of the YBCO layers over a remarkably long range of several tens of nanometres. The transfer of the electron-phonon coupling between superlattice layers can be understood as a consequence of long-range Coulomb forces in conjunction with an orbital reconstruction at the interface. The superlattice geometry thus provides new opportunities for controlled modification of the electron-phonon interaction in complex materials.
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http://dx.doi.org/10.1038/nmat3378 | DOI Listing |
Phys Rev Lett
December 2024
Chalmers University of Technology, Department of Physics, 412 96 Göteborg, Sweden.
The phonon inverse Faraday effect describes the emergence of a dc magnetization due to circularly polarized phonons. In this work we present a microscopic formalism for the phonon inverse Faraday effect. The formalism is based on time-dependent second order perturbation theory and electron phonon coupling.
View Article and Find Full Text PDFPNAS Nexus
January 2025
The Harrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, MI 48109-1040, USA.
The direct, ultrafast excitation of polar phonons with electromagnetic radiation is a potent strategy for controlling the properties of a wide range of materials, particularly in the context of influencing their magnetic behavior. Here, we show that, contrary to common perception, the origin of phonon-induced magnetic activity does not stem from the Maxwellian fields resulting from the motion of the ions themselves or the effect their motion exerts on the electron subsystem. Through the mechanism of electron-phonon coupling, a coherent state of circularly polarized phonons generates substantial non-Maxwellian fields that disrupt time-reversal symmetry, effectively emulating the behavior of authentic magnetic fields.
View Article and Find Full Text PDFNanoscale Adv
December 2024
Department of Biological Sciences and Engineering, Indian Institute of Technology Palakkad Palakkad Kerala 678 623 India.
Since the initial publication on the first TiCT MXene in 2011, there has been a significant increase in the number of reports on applications of MXenes in various domains. MXenes have emerged as highly promising materials for various biomedical applications, including photothermal therapy (PTT), drug delivery, diagnostic imaging, and biosensing, owing to their fascinating conductivity, mechanical strength, biocompatibility and hydrophilicity. Through surface modification, MXenes can mitigate cytotoxicity, enhance biological stability, and improve histocompatibility, thereby enabling their potential use in biomedical applications.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Mechanical Engineering, the University of Texas at Dallas, Richardson, Texas 75080, United States.
Plasmonic nanomaterials are effective photoacoustic (PA) contrast agents with diverse biomedical applications. While silica coatings on gold nanoparticles (AuNPs) have been demonstrated to increase PA efficiency, the underlying mechanism remains elusive. Here, we systematically investigated the impact of silica coatings on PA generation under picosecond and nanosecond laser pulses.
View Article and Find Full Text PDFNano Lett
January 2025
State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China.
Lanthanide (Ln)-titanium-based molecular nanoclusters (NCs) have attracted much attention due to their atomically precise total structure and promising optical behavior, while there is still minimal cognition of structure-dictated electron relaxation dynamics in such an NCs regime with unsatisfied photoluminescence quantum yield (PLQY, in general below 20%). Herein, the photoexcited small polarons (i.e.
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