Occurrence, biosynthesis, and biodegradation of pivalic acid and other compounds, having a quaternary carbon atom by different bacteria, are described. We have summarized the relevant data that have so far been published, presenting them in a graphical form, i.e., as biodegradation pathways including B₁₂-dependent isomerization and desaturation that lead to the degradation of pivalic acid and similar compounds to products with other than quaternary carbon atoms, i.e., compounds whose catabolism is well known.
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http://dx.doi.org/10.1007/s00253-012-4267-x | DOI Listing |
Inorg Chem
November 2024
School of Chemistry, University of Hyderabad, Hyderabad 500046, India.
ACS Catal
July 2024
Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States.
Fe(II) carboxylates react with dioxygen and carboxylic acid to form Fe(μ-OH)(μ-O)(μ-X)(HX) (X = acetate or pivalate), which is an active oxidant for Rh-catalyzed arene alkenylation. Heating (150-200 °C) the catalyst precursor [(η-CH)Rh(μ-OAc)] with ethylene, benzene, Fe(II) carboxylate, and dioxygen yields styrene >30-fold faster than the reaction with dioxygen in the absence of the Fe(II) carboxylate additive. It is also demonstrated that Fe(μ-OH)(μ-O)(μ-X)(HX) is an active oxidant under anaerobic conditions, and the reduced material can be reoxidized to Fe(μ-OH)(μ-O)(μ-X)(HX) by dioxygen.
View Article and Find Full Text PDFOrganometallics
June 2024
Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States.
We report the conversion of anisoles and olefins to alkenyl anisoles via a transition-metal-catalyzed arene C-H activation and olefin insertion mechanism. The catalyst precursor, [(η-CH)Rh(μ-OAc)], and the in situ oxidant Cu(OPiv) (OPiv = pivalate) convert anisoles and olefins (ethylene or propylene) to alkenyl anisoles. When ethylene is used as the olefin, the // ratio varies between approximately 1:3:1 (selective for 3-methoxystyrene) and 1:5:10 (selective for 4-methoxystyrene).
View Article and Find Full Text PDFIn Silico Pharmacol
May 2024
Department of Biochemistry, Faculty of Basic Medical Sciences, University of Lagos, Lagos, Nigeria.
East Africa ( spp.), notably , "Matooke" a staple and economically important food in the region. Here, 12 selected .
View Article and Find Full Text PDFMolecules
May 2024
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp., 119991 Moscow, Russia.
Interaction of the pre-organized complex of iron(II) trimethylacetate and 1,10-phenanthroline (phen) [Fe(piv)(phen)] () (piv = (Me)CCO)) with 1,6-diaminohexane (dahx) in anhydrous acetonitrile yielded a 1D coordination polymer [FeO(piv)(dahx)] () and an organic salt of pivalic acid (Hdahx)(piv) (). The structure of the obtained compounds was determined by single-crystal X-ray diffraction analysis. The phase purity of the complexes was determined by powder X-ray diffraction analysis.
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