Reaction of a nickel(0) carbonyl complex, K(2)[L(tBu)NiCO](2), with N(2)O generates a cyclic carbonate compound composed of six [Ni(II)(CO(3))K](+) units. The same product can also be obtained using O(2) as the oxidant in a solid-state/gas reaction. These conversions represent unique examples of a nickel-bound CO oxidation by N(2)O and O(2), respectively.
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| http://dx.doi.org/10.1039/c2cc33846g | DOI Listing |
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