2,3-Dihydro-pyrrolo-[2,1-b]quinazoline-9(1H)-thione.

Acta Crystallogr Sect E Struct Rep Online

S. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan, Mirzo Ulugbek Str. 77, Tashkent 100170, Uzbekistan.

Published: June 2012

In the crystal, mol-ecules of the title compound, C(11)H(10)N(2)S, are connected by C-H⋯N inter-actions around threefold axes. Furthermore, they form stacks along the c axis showing π-π inter-actions between pyrimidine rings [centroid-centroid distance = 3.721 (1) Å]. The central ring is essentially planar with an r.m.s. deviation of 0.007 Å. The five-membered ring adopts an envelope conformation with the flap atom deviating by 0.241 (4) Å from the mean plane (r.m.s. deviation = 0.002 Å) through the other four ring atoms.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379333PMC
http://dx.doi.org/10.1107/S1600536812021228DOI Listing

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