12α-Hy-droxy-3,27-dioxooleanano-28,13-lactone.

Acta Crystallogr Sect E Struct Rep Online

Center of Separation Technology, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, People's Republic of China.

Published: June 2012

There are two independent mol-ecules in the asymmetric unit of the title compound, C(30)H(44)O(5). They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent mol-ecules the D rings adopt a slightly distorted half-chair conformation due the presence of the lactone ring while the other four six-membered rings all adopt chair conformations. The characteristic carbon-carbon double bond of the oleanoic skeleton is absent. Inter-molecular O-H⋯O hydrogen bonds between the hy-droxy and carbonyl groups occur in the crystal structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379199PMC
http://dx.doi.org/10.1107/S1600536812017783DOI Listing

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