The title compound, [CdBr(2)(C(13)H(12)N(4)O)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with meth-yl(pyridin-2-yl)methanone picolinoylhydrazone and sodium bromide. The Cd(2+) cation is ligated by one O atom and two N atoms of the tridentate ligand and two bromide anions, forming a Br(2)CdN(2)O polyhedron with a distorted trigonal-bipyramidal coordination geometry. In the crystal, non-classical C-H⋯Br hydrogen bonds are observed. In addition, π-π stacking inter-actions [centroid-centroid distance = 3.7455 (19) Å] contribute to the stabilization of the crystal structure.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379182 | PMC |
| http://dx.doi.org/10.1107/S1600536812023185 | DOI Listing |
Publication Analysis
Top Keywords
dibromido{n'-[1-pyridin-2-ylethyl-idene]picolinohydrazide-κ2n'o}cadmium title
4
title compound
4
compound [cdbr2c13h12n4o]
4
[cdbr2c13h12n4o] reaction
4
reaction cdno32·4h2o
4
cdno32·4h2o meth-ylpyridin-2-ylmethanone
4
meth-ylpyridin-2-ylmethanone picolinoylhydrazone
4
picolinoylhydrazone sodium
4
sodium bromide
4
bromide cd2+
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!