The cupferronate ions in the centrosymmetric dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometries of the five-coordinate Pb(II) atoms in the two independent mol-ecules are Ψ-octa-hedral; if more remote Pb⋯O inter-actions are also considered, the coordination number is increased to six for one mol-ecule and to seven for the other. Their coordination polyhedra are ill defined in the chain motif, which runs along [100].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379120PMC
http://dx.doi.org/10.1107/S1600536812021885DOI Listing

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