catena-Poly[[[bis-(acetato-κ(2)O,O')aqua-cadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ(2)N:N'] dihydrate].

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.

Published: June 2012

In the title complex, {[Cd(CH(3)COO)(2)(C(11)H(8)N(2)O)(H(2)O)]·2H(2)O}(n), the Cd(II) ion adopts an O(5)N(2) penta-gonal-bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ(2)-bridging mode, linking the metal atoms, leading to an infinite chain along [-110]. O-H⋯O hydrogen bonds involving the lattice water mol-ecules connect these chains into a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379068PMC
http://dx.doi.org/10.1107/S1600536812019101DOI Listing

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