The results obtained from molecular dynamics simulations of the friction at an interface between polymer melts and weakly attractive crystalline surfaces are reported. We consider a coarse-grained bead-spring model of linear chains with adjustable intrinsic stiffness. The structure and relaxation dynamics of polymer chains near interfaces are quantified by the radius of gyration and decay of the time autocorrelation function of the first normal mode. We found that the friction coefficient at small slip velocities exhibits a distinct maximum which appears due to shear-induced alignment of semiflexible chain segments in contact with solid walls. At large slip velocities, the friction coefficient is independent of the chain stiffness. The data for the friction coefficient and shear viscosity are used to elucidate main trends in the nonlinear shear rate dependence of the slip length. The influence of chain stiffness on the relationship between the friction coefficient and the structure factor in the first fluid layer is discussed.
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http://dx.doi.org/10.1063/1.4728106 | DOI Listing |
ACS Nano
December 2024
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 1H9, Canada.
Nanometer-thick ultrathin coatings with superior mechanical strength and desirable lubricating and antifouling performance are critical for the miniaturization of implantable medical devices. However, integrating these properties at the nanoscale remains challenging due to the inherent trade-off between mechanical strength and hydration as well as limitations in coating thickness. In this work, we address these challenges by employing dual-function metal coordination to construct a ∼25 nm thick bilayer structure.
View Article and Find Full Text PDFMar Drugs
December 2024
College of Metrology Measurement and Instrument, China Jiliang University, Hangzhou 310018, China.
The adhesion of marine organisms to marine facilities negatively impacts human productivity. This phenomenon, known as marine fouling, constitutes a serious issue in the marine equipment industry. It increases resistance for ships and their structures, which, in turn, raises fuel consumption and reduces ship speed.
View Article and Find Full Text PDFCVIR Endovasc
December 2024
Department of Cardiovascular Medicine, Osaka Metropolitan University Graduate School of Medicine, 1-4-3 Asahimachi Abenoku, Osaka, 545-8585, Japan.
Background: Fractional flow reserve (FFR) can be estimated by analysis of intravascular imaging in a coronary artery; however, there are no data for estimated FFR in an extremity artery. The aim of this concept-generating study was to determine whether it is possible to estimate the value of peripheral FFR (PFFR) by intravascular ultrasound (IVUS) analysis also in femoropopliteal artery lesions.
Methods: Between April 2022 and February 2023, PFFR was measured before endovascular therapy in 31 stenotic femoropopliteal artery lesions.
PLoS One
December 2024
Key Laboratory of Intelligent Construction and Maintenance of CAAC, Xi'an, Shaanxi, China.
This study aimed to investigate the influence of different coarse aggregate mineral compositions on the skid resistance performance of asphalt pavement. The imprint method was utilized to assess the contact probability between various graded asphalt surface aggregates and tires. Additionally, macroscopic adhesive friction coefficients between polished surfaces of three types of rock slabs (basalt, limestone, granite) and rubber were determined using a pendulum friction tester.
View Article and Find Full Text PDFNano Lett
December 2024
Innovation Center for Textile Science and Technology, College of Textiles, Donghua University, Shanghai 200051, China.
Increasing noise pollution has generated a tremendous threat to human health and incurred great economic losses. However, most existing noise-absorbing materials present a significant challenge in achieving lightweight, robust mechanical stability, and efficient low-frequency (<1000 Hz) noise reduction. Herein, we create highly compressible micro/nanofibrous sponges with thin-walled cavity structures for efficient noise reduction through electrospinning and dispersion casting.
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