Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp(2)VCl(2) catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3375726 | PMC |
http://dx.doi.org/10.1039/C2SC20178J | DOI Listing |
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