Interference, coupling, and nonlinear control of high-order modes in single asymmetric nanoantennas.

ACS Nano

SEPnet and Physics and Astronomy, Faculty of Physical and Applied Sciences, University of Southampton, Highfield, Southampton SO17 1BJ, United Kingdom.

Published: July 2012

We investigate theoretically and experimentally the structure of plasmonic modes in individual asymmetric dimer antennas. Plasmonic near-field coupling of high-order modes results in hybridization of bright and dark modes of the individual nanorods, leading to an anticrossing of the coupled resonances. For two bright modes, hybridization results in a capacitive red shift and super-radiant broadening. We show that the properties of asymmetric dimers can be used for nonlinear control of spectral modes and demonstrate such a nonlinear effect by measuring the modulation of a hybrid asymmetric dimer--ITO antenna. With use of full electrodynamical calculations, we find that the properties of the near-field nonlinear responses are distinctly different from the far-field, which opens up new routes for nonlinear control of plasmonic nanosystems.

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http://dx.doi.org/10.1021/nn3021579DOI Listing

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