A chemosensor for dihydrogenphosphate based on an oxoazamacrocycle possessing three thiourea arms.

Org Biomol Chem

Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain.

Published: July 2012

We report a new H-bond macrocyclic chromogenic chemosensor in organic media, H(3)L, which displayed drastic changes in its UV-vis spectra revealing selectivity for dihydrogenphosphate over other inorganic anions, such as acetate or fluoride. The X-ray crystal structures of the [H(4)L···NO(3)]·(CH(3)CN)(4) and [H(4)L···CF(3)CO(2)]·(CH(3)CN)(2) salt complexes are also reported.

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Source
http://dx.doi.org/10.1039/c2ob25498kDOI Listing

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