Fabrication and optical emission of TiO2-sheathed ZnO nanowires.

J Nanosci Nanotechnol

Department of Materials Science and Engineering, Inha University, 253 Yonghyeon-Dong, Incheon 402-751, Republic of Korea.

Published: February 2012

The ZnO nanowires were synthesized by using vapor-liquid-solid mechanism and then the ZnO nanowires were sheathed with TiO2 by metal organic chemical vapor deposition. The coaxial nanowires were 30-200 nm in diameter and up to 0.2 microm in length. Transmission electron microscopy and X-ray diffraction analysis results showed that the ZnO cores and TiO2 shells of the core-shell nanowires had wurtzite and amorphous structures, respectively. Photoluminescence measurement showed that TiO2 coating increased and decreased the near-band edge (NBE) and deep-level emissions of the ZnO nanowires in intensity, respectively. However, it appeared that subsequent annealing was undesirable since it decreased the NBE emission in intensity.

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http://dx.doi.org/10.1166/jnn.2012.4649DOI Listing

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