In theory, glass diverted or recovered from the municipal solid waste (MSW) stream can be used as feedstock (glass cullet) in the production of new glass containers. However, post-consumer glass typically contains a mixture of clear and coloured material and is often contaminated with other wastes; characteristics that are impediments to the production of new containers. Sorting and cleaning of glass diverted from MSW to make it feasible for use in bottle industries are also time consuming and costly tasks. There is, however, the potential to use recycled glass as a sub-base material for road pavement construction. Geotechnical investigations to date suggest that use of recycled glass as a roadway sub-base could be cost-effective, and thus preclude the need for expensive sorting. There is, however, the necessessity to further investigate the potential short- and long-term toxicity, health hazards, and/or environmental pollution associated with use of mixed glass cullet as an aggregate, considering conditions during stockpiled storage and after placement. The results of laboratory tests on recycled glass regarding its potential to release pollutants to the environment via leaching are presented herein. Five random samples of crushed glasses were collected from a recycling company in Melbourne, Australia. The parameters tested for each sample were total organic matter, heavy metals, sulfates, chlorides, conductivity, pH and surfactant levels. It wais found that in most cases, the contamination levels were within the State of Victoria's Environmental Protection Agency-specified limits for manual handling, thus indicating that recycled glass could probably be safely used in pavement sub-bases.
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http://dx.doi.org/10.1177/0734242X12448512 | DOI Listing |
Macromolecules
January 2025
Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, U.K.
A series of novel chain-extended polyurethanes (CEPUs) featuring degradable sulfonyl ethyl urethane chain-extenders that permit degradation under base-triggered conditions to afford "debond-on-demand" elastomeric adhesives are reported. Exposure of the CEPUs to -butylammonium fluoride (TBAF) triggered the degradation of the sulfonyl ethyl urethane chain-extenders. Lap shear adhesion tests of the CEPUs exposed to TBAF revealed reductions in shear strength of up to 65% for both aluminum and glass substrates, from 2.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Textile Engineering, Faculty of Engineering, Rajamangala University of Technology Thanyaburi, Pathum Thani 12110, Thailand.
This study investigates the reinforcement of cement paste with woven fabrics made from recycled poly(ethylene terephthalate) (PET) bottle yarn, aiming to enhance its mechanical properties while addressing PET waste. PET bottles were transformed into yarn with a denier of 3,593.8, strength of 91.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Colorado State University, Chemistry and Biochemistry, 301 W. Pitkin Street, 215 UCB, 80523, United States, 80523, Fort Collins, UNITED STATES OF AMERICA.
Synthetic polymers have found widespread use with functional lifetimes from seconds to decades. However, the lack of end-of-life treatment for these plastics is causing a significant environmental and human health crisis due to their persistence and bioaccumulation. Upcycling post-consumer plastic waste to products with inherent recyclability is an attractive strategy to tackle this problem, as it can broaden the range of accessible materials and uncover unprecedented features while dealing with current plastic waste.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China.
The increasing demand for energy in cooling systems due to global warming presents a significant challenge. Conventional air-conditioning methods exacerbate climate change by contributing to heightened carbon emissions. Glass facades, renowned in modern architecture for their versatility and aesthetic appeal, inadvertently trap solar radiation, resulting in heat buildup and the greenhouse effect.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Department of Chemical Engineering, Materials, Environment, Sapienza University of Rome, 00184 Rome, Italy.
Cleavable bio-based epoxy resin systems are emerging, eco-friendly, and promising alternatives to the common thermoset ones, providing quite comparable thermo-mechanical properties while enabling a circular and green end-of-life scenario of the composite materials. In addition to being designed to incorporate a bio-based resin greener than the conventional fully fossil-based epoxies, these formulations involve cleaving hardeners that enable, under mild thermo-chemical conditions, the total recycling of the composite material through the recovery of the fiber and matrix as a thermoplastic. This research addressed the characterization, processability, and recyclability of a new commercial cleavable bio-resin formulation (designed by the R-Concept company) that can be used in the fabrication of fully recyclable polymer composites.
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