A highly effective silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes has been developed. The reactions provide ready access to a wide range of siloxy naphthalenes and anthracenes, which are formed in good to high yields, under mild reaction conditions, using low catalyst loadings.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415592 | PMC |
| http://dx.doi.org/10.1021/ja302537j | DOI Listing |
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