The racemic title compound, C(9)H(11)NO(4)·H(2)O, a tricyclic rearranged amino-norbornane dicarb-oxy-lic acid, is a conformationally rigid analogue of glutamic acid and exists as an ammonium-carboxyl-ate zwitterion, with the bridghead carb-oxy-lic acid group anti-related. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds involving the ammonium, carb-oxy-lic acid and water donor groups with both water and carboxyl O-atom acceptors give a three-dimensional framework structure.
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http://dx.doi.org/10.1107/S1600536812016236 | DOI Listing |
IUCrdata
December 2024
University of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany.
The title compound, CHO, was prepared from α-pinene in three steps. The ester and acid moieties are on the slightly folded cyclo-butane ring. In the crystal, carb-oxy-lic acid bound dimers form layers parallel to (202).
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January 2025
Oligometrics, Inc., 2510 47th Street, Suite 208, Boulder, CO, 80301, USA.
The X-ray crystal structure of a multi-aromatic substituted 1,2,3-triazole is presented, which shows an extensive three-dimensional hydrogen-bonding network involving two water mol-ecules and two aceto-nitrile mol-ecules. The structure of 4-{[(4-{[1-({[(3,4-di-meth-oxy-phen-yl)meth-yl](3-acetamido-phen-yl)carbamo-yl}meth-yl)-1-1,2,3-triazol-4-yl]meth-oxy}-3-meth-oxy-phen-yl)meth-yl]amino}-benzoic acid-aceto-nitrile-water (1/2/2), CHNO·2CHN·2HO, features amine-linked aromatic groups that have a variety functionality including a carb-oxy-lic acid, an acetamido group, and meth-oxy ethers. All -H groups, and seven out of ten heteroatoms with available lone-pair electrons, participate in hydrogen bonding, with the aid of dimer-bridging water mol-ecules and aceto-nitrile mol-ecules whose methyl groups form close contacts with oxygen atoms.
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October 2024
Nelson Mandela University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.
The title compound, CHO, is an α-hy-droxy-carb-oxy-lic acid whose ortho-rhom-bic polymorph has been reported earlier [Qiu (2007 ▸). , , 1819-1824]. The asymmetric unit contains two complete mol-ecules.
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September 2024
Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, 100125, M. Ulugbek Str. 83, Tashkent, 700125, Uzbekistan.
The title compound, (CHNO)[CuCl(CHNO)]·2HO, was prepared by reacting Cu acetate dihydrate, solid 8-hy-droxy-quinoline (8-HQ), and solid pyridine-2,6-di-carb-oxy-lic acid (Hpydc), in a 1:1:1 molar ratio, in an aqueous solution of dilute hydro-chloric acid. The Cu atom exhibits a distorted CuONCl octa-hedral geometry, coordinating two oxygen atoms and one nitro-gen atom from the tridentate Hpydc ligand and three chloride atoms; the nitro-gen atom and one chloride atom occupy the axial positions with Cu-N and Cu-Cl bond lengths of 2.011 (2) Å and 2.
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September 2024
Department of Chemistry, Faculty of Natural and Agricultural Sciences, University of Pretoria, Pretoria, South Africa.
The mol-ecular structure of CHO, (+)-diplodiatoxin, is described, whereby the absolute configuration of the structure of diplodiatoxin has been confirmed by single-crystal X-ray diffraction. Diplodiatoxin crystallizes in the chiral 422 space group with one mol-ecule in the asymmetric unit.
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