In the title compound, C(21)H(23)NOS, the thia-zolidine ring adopts a twist conformation about one of its C-S bonds, while the cyclo-hexane ring has a chair conformation. The S and N atoms attached to the spiro C atom are in axial and equatorial orientations, respectively. The thia-zolidine ring forms dihedral angles of 86.24 (14) and 31.82 (15)° with the directly attached and remote terminal benzene rings, respectively. The dihedral angle between the two terminal benzene rings is 86.74 (14)°. In the crystal, the only significant directional inter-action is a weak C-H⋯π bond, which generates [010] chains.
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http://dx.doi.org/10.1107/S1600536812015358 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
October 2020
Organic Chemistry Department, Baku State University, Z. Khalilov str. 23, Az, 1148 Baku, Azerbaijan.
In the cation of the title salt, CHNS·Br·CHNO, the central thia-zolidine ring adopts an envelope conformation with puckering parameters (2) = 0.310 (3) Å and (2) = 42.2 (6)°.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
March 2020
Organic Chemistry Department, Baku State University, Z. Xalilov str. 23, Az, 1148 Baku, Azerbaijan.
The central thia-zolidine ring of the title salt, CHNS·Br, adopts an envelope conformation, with the C atom bearing the phenyl ring as the flap atom. In the crystal, the cations and anions are linked by N-H⋯Br hydrogen bonds, forming chains parallel to the -axis direction. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (46.
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February 2020
Department of Chemistry, Government Arts College, Tiruchirappalli- 620 022, Tamil Nadu, India.
In the title compound, CHBrNOS, a key inter-mediate in the synthesis of the widely used β-lactamase inhibitor tazobactam, the five-membered thia-zolidine ring adopts an envelope conformation and the four-membered azetidine ring is in a distorted planar conformation. The crystal structure features C-H⋯O hydrogen bonds and a weak C-H⋯π inter-action.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
October 2019
Organic Chemistry Department, Baku State University, Z. Xalilov str. 23, Az, 1148 Baku, Azerbaijan.
In the cation of the title salt, CHNS·Br, the thia-zolidine ring adopts an envelope conformation with the C atom adjacent to the phenyl ring as the flap. In the crystal, N-H⋯Br hydrogen bonds link the components into a three-dimensional network. Weak π-π stacking inter-actions between the phenyl rings of adjacent cations also contribute to the mol-ecular packing.
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August 2019
Organic Chemistry Department, Baku State University, Z. Xalilov str. 23, Az, 1148 Baku, Azerbaijan.
The title salt, CHClNS·Br, is isotypic with ()-3-[(4-fluoro-benzyl-idene)amino]-5-phenyl-thia-zolidin-2-iminium bromide [Khalilov (2019 ▸). . E, 662-666].
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