2-Carb-oxy-6-(quinolin-1-ium-8-yl-oxy)benzoate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Fuzhou, Fuzhou 350108, People's Republic of China.

Published: May 2012

In the zwitterionic title compound, C(17)H(11)NO(5), the dihedral angle between the two aromatic rings is 76.90 (7)°. The dihedral angles between the carboxyl groups and the benzene ring are 64.02 (9) and 21.67 (9)°, the larger angle being associated with an intra-molecular N-H⋯O(carbox-yl) hydrogen bond, resulting from proton transfer from the carb-oxy-lic acid group to the quinoline N atom and giving an S(9) ring motif. In the crystal, mol-ecules are connected by O-H⋯O hydrogen bonds into chains extending along the b-axis direction. An overall two-dimensional network structure is formed through π-π inter-actions between the quinoline rings [minimum ring-centroid separation = 3.6068 (6) Å].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344484PMC
http://dx.doi.org/10.1107/S1600536812013980DOI Listing

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