In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(CH(3)OH)(2)(H(2)O)](n), an infinite chain is formed along the b axis by linking of the Zn(OH(2))(CH(3)OH)(2) unit with one carboxyl-ate group of the furan-2,5-dicarboxyl-ate ligand. The Zn(II) ion is in a distorted octa-hedral environment with one weak coordination [Zn-O(carboxyl-ate) = 2.565 (3) Å] and two meth-anol mol-ecules located in axial positions. In the chain, O(water)-H⋯O hydrogen bonds are present, while adjacent chains are linked by O(methanol)-H⋯O hydrogen bonds into a layer parallel to (10-2).
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http://dx.doi.org/10.1107/S1600536812014936 | DOI Listing |
ACS Appl Mater Interfaces
March 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China.
Developing vapor-solid reaction methods to prepare organic-inorganic hybrid perovskite thin films is highly compatible with processes in crystalline silicon solar cells and the thin-film photovoltaic industries, facilitating rapid industrialization. In the vapor-solid reaction, the crystallization quality of perovskite thin films is widely influenced by the crystallinity and microstructure of lead iodide (PbI) precursor films. During the thermal evaporation process of preparing the PbI precursor films, we observed that PbI tends to develop a disordered surface morphology and exhibits high crystallinity, which significantly hinders the uniform diffusion of the organic amine salt vapor during the subsequent vapor-solid reaction.
View Article and Find Full Text PDFACS Nano
March 2025
School of Environmental and Materials Engineering, Yantai University, Yantai 264005, China.
Zinc-ion batteries become a major research focus in energy storage, valued for their low cost and high safety. However, their widespread application is hindered by poor zinc anode stability caused by dendrites, side reactions, and poor performance across a wide temperature range at a strong hydrogen bond network aqueous electrolyte. In this study, we propose a strategy for the synergistic combination of a polyacrylamide hydrogel with sucrose.
View Article and Find Full Text PDFJ Genet Eng Biotechnol
March 2025
Centre for Interdisciplinary Research in Basic Sciences, Jamia Millia Islamia, Jamia Nagar, New Delhi 110025, India. Electronic address:
Background: Cancer remains an awful challenge, despite years of targeting proteins to control its relentless growth and spread. Fungal metabolites, a treasure of natural chemicals, offer a glimmer of hope. Telomeres, the cellular "caps," are a focal point in cancer research.
View Article and Find Full Text PDFJ Genet Eng Biotechnol
March 2025
State Key Laboratory of Pathogenesis, Prevention and Treatment of High Incidence Diseases in Central Asia, China; Department of Hepatobiliary and Echinococcosis Surgery, First Affiliated Hospital of Xinjiang Medical University, Urumqi 830011, China. Electronic address:
Background: Few studies revealed that stromal genes regulate the tumor microenvironment (TME). However, identification of key-risk genes in the invasive ductal breast carcinoma-associated stroma (IDBCS) and their associations with the prediction of risk group remains lacking.
Methods: This study used the GSE9014, GSE10797, GSE8977, GSE33692, and TGGA BRCA datasets.
Fitoterapia
March 2025
CAS Key Laboratory of Forest Ecology and Silviculture, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China. Electronic address:
Oxidative stress significantly contributes to the progression of diabetes. The use of antioxidants or α-glycosidase inhibitors would be an effective therapeutic strategy for diabetes. To discover natural antioxidants or α-glycosidase inhibitors, two new compounds, penidione A (1) and peniorcinol D (2), were obtained from the endophytic fungus Penicillium brefeldianum F4a isolated from the roots of Houttuynia cordata Thunb.
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