The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol-ecule and one disordered dimethyl-formamide solvent mol-ecule. The Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by two N, two O and two S atoms. An intra-molecular C-H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked through inter-molecular N-H⋯S, N-H⋯O, C-H⋯N, C-H⋯O and C-H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C-H⋯π inter-actions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344298PMC
http://dx.doi.org/10.1107/S1600536812012834DOI Listing

Publication Analysis

Top Keywords

c-h⋯s hydrogen
8
bis[2-2-oxoindolin-3-yl-idene-n-phenylhydrazinecarbothio-amidato-κ3on2s]nickelii dimethyl-formamide
4
dimethyl-formamide monosolvate
4
monosolvate asymmetric
4
asymmetric unit
4
unit title
4
title compound
4
compound [nic15h11n4os2]·c3h7no
4
[nic15h11n4os2]·c3h7no niii
4
niii complex
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!