The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015-1017].
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| http://dx.doi.org/10.1107/S1600536812012494 | DOI Listing |
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