(Acetyl-acetonato-κ(2)O,O')carbon-yl[tris-(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate.

Acta Crystallogr Sect E Struct Rep Online

Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, 2006 Johannesburg, South Africa.

Published: April 2012

The title compound, [Rh(C(5)H(7)O(2))(C(30)H(21)P)(CO)]·0.5C(3)H(6)O, has two different complex molecules in the asymmetric unit, with the Rh(I) atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343806PMC
http://dx.doi.org/10.1107/S1600536812008148DOI Listing

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