AI Article Synopsis
- - Reduction of imine-anthracenone compounds leads to the formation of secondary alcohols while keeping the external imine group intact.
- - The presence of Zn(II) ions triggers a unique metal-mediated reaction that converts imine compounds into enamine forms.
- - This process introduces a novel fluorescence detection method specifically for Zn(II), which hasn't been documented before.
Article Abstract
Reduction of imine-anthracenone compounds selectively produces secondary alcohols leaving the external imine group unreacted. Addition of the Zn(II) ion induces a metal-mediated imine-enamine tautomerization reaction that is selective for Zn(II), a new fluorescence detection method not previously observed for this important cation.
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| http://dx.doi.org/10.1021/ol300874c | DOI Listing |
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