Much stronger binding is seen in aqueous solutions between the anionic polyelectrolyte potassium poly(vinyl sulfate) and the substitution labile aluminium(III) than with the kinetically inert chromium(III). This strongly supports the idea that entropy driven water loss from the hydration sphere of the metal ion plays a major role in driving binding of the trivalent metal ion to the polyelectrolyte.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2cp40480j | DOI Listing |
Publication Analysis
Top Keywords
metal ion
8
cation dehydration
4
dehydration drive
4
drive binding
4
binding metal
4
metal ions
4
ions polyelectrolytes
4
polyelectrolytes water?
4
water? learn
4
learn behaviour
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!