The synthesis of recyclable ionic liquid-supported imidazolidinone catalyst I and its application in 1,3-dipolar cycloaddition of nitrone with α,β-unsaturated aldehyde with high performance were described. Most importantly, the catalyst I can be recovered and recycled for up to five runs without observing significant decrease in catalytic activity.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2cc31830j | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Recyclable Nano Zero-Valent Iron (nZVI)-Catalyst-Mediated Sustainable Photopolymerization of Glycidyl Methacrylate in Ionic Liquid and Functional Copolymers Thereof.
Macromol Rapid Commun
January 2025
Department of Chemistry, Indian Institute of Technology Bhilai, Durg, Chhattisgarh, 491002, India.
Utilization of reusable catalysts and reaction media has recently been an area of interest to devise a sustainable approach. Interestingly, photoinduced reversible deactivation radical polymerization (photoRDRP) of glycidyl methacrylate (GMA) is achieved with reusable and magnetically separable nano zero-valent Iron (nZVI). This resulted in well-defined poly(glycidyl methacrylate) (PGMA) (upto 22700 g mol) with a low dispersity (Đ ≤ 1.
View Article and Find Full Text PDFMagnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach.
Sci Rep
January 2025
Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran.
In this project, a new heterogeneous polymeric ionic liquid catalyst based on vinylimidazole, stabilized on magnetic nanoparticles )FeO@AlO@[PBVIm]HSO) was prepared. Then the desired catalyst was identified by TGA, FT-IR, VSM, and TEM techniques. The efficiency of this catalyst was measured in the synthesis of chromene, xanthene, and dihydropyrimidinone.
View Article and Find Full Text PDFEngineering silica nanocoated whole-cell asymmetric biocatalyst for efficient preparation of a key chiral intermediate of (S)-Rivastigmine.
J Biotechnol
January 2025
Key Laboratory for Molecular Enzymology and Engineering of Ministry of Education, School of Life Sciences, Jilin University, Changchun 130012, China. Electronic address:
In our previous study, the whole cells containing an aldo-keto reductase (yhdN) and glucose dehydrogenase (GDH) were constructed and applied in a stereoselective carbonyl reduction reaction to prepare (S)-NEMCA-HEPE, being a key chiral intermediate of (S)-Rivastigmine which is widely prescribed for the treatment of Alzheimer's disease. Although the conversion and enantiomeric excess (e.e.
View Article and Find Full Text PDFMulti-effect synergistic induction of unsaturated MnO on sandy sediment for enhanced manganese adsorption and byproduct resource recovery in solar evaporation.
J Hazard Mater
January 2025
School of Ecology and Environment, Zhengzhou University, 100 Kexue Avenue, Zhengzhou 450001, PR China; Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection, Zhengzhou 450001, PR China. Electronic address:
The efficient removal of Mn(II) from wastewater is crucial for safeguarding water quality, yet existing adsorbents face significant challenges, including high costs, poor resistance to ionic interference, and scalability limitations. This study addresses these challenges by utilizing abundant natural sandy sediment (SS) as a substrate to load unsaturated MnO via in-situ oxidation, creating a novel adsorbent (MOSS). MOSS exhibits a remarkable Mn(II) adsorption capacity of 1.
View Article and Find Full Text PDFRecovery of iron as hematite and separation of trivalent lanthanide ions from spent hard disk magnet leach liquor using [P66614][Cy272] ionic liquid.
RSC Adv
January 2025
Department of Chemistry, Institute of Technical Education and Research, Siksha 'O' Anusandhan Deemed to Be University Bhubaneswar-751030 Odisha India
The widespread use of neodymium-iron-boron (NdFeB) magnets has raised concerns about the environmental impact of their disposal, prompting the need for sustainable recycling strategies. Traditional solvents used in recycling are toxic and flammable, making them risky to use. Ionic liquids are safer and greener options with low vapor pressure, high stability, and less flammability.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!