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http://dx.doi.org/10.1002/anie.201107938 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Universidad Complutense de Madrid Facultad de Ciencias Quimicas, Inorganic Chemistry Department, 28034, Madrid, SPAIN.
Achieving high battery performance from low-cost, easily synthesisable electrode materials is crucial for advancing energy storage technologies. Metal organic frameworks (MOFs) combining inexpensive transition metals and organic ligands are promising candidates for high-capacity cathodes. Iron-chloranilate-water frameworks are herein reported to be produced in aqueous media under mild conditions.
View Article and Find Full Text PDFNat Commun
January 2025
The Faculty of Data and Decisions Sciences, Technion - Israel Institute of Technology, Haifa, Israel.
Large Language Models (LLMs) have shown success in predicting neural signals associated with narrative processing, but their approach to integrating context over large timescales differs fundamentally from that of the human brain. In this study, we show how the brain, unlike LLMs that process large text windows in parallel, integrates short-term and long-term contextual information through an incremental mechanism. Using fMRI data from 219 participants listening to spoken narratives, we first demonstrate that LLMs predict brain activity effectively only when using short contextual windows of up to a few dozen words.
View Article and Find Full Text PDFBrain Lang
January 2025
Department of Linguistics, Graduate School of Arts & Letters, Tohoku University, Sendai, Japan. Electronic address:
This study examines the neural mechanisms behind integrating syntactic and information structures during sentence comprehension using functional Magnetic Resonance Imaging. Focusing on Japanese sentences with canonical (SOV) and non-canonical (OSV) word orders, the study revealed distinct neural networks responsible for processing these linguistic structures. The left opercular part of the inferior frontal gyrus, left premotor area, and left posterior superior/middle temporal gyrus were primarily involved in syntactic processing.
View Article and Find Full Text PDFPsychiatry Res Neuroimaging
January 2025
Departamento de Morfologia e Genética, Escola Paulista de Medicina, Universidade Federal de São Paulo - UNIFESP, São Paulo, SP, Brazil. Electronic address:
Alcohol use disorder (AUD) is a multifactorial disease closely related to neurodevelopment and environmental factors that influence behavior. This study explored the relationships between brain volume and behavior from an Exploratory Structural Equation Modeling (ESEM) based on the Research Domain Criteria. High-resolution magnetic resonance imaging scans were acquired from recent patients with AUD (n = 50) and healthy controls (HC=50).
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
College of Physics, Sichuan University, Chengdu, 610065, China.
Magnetic semiconductors with spin-polarized non-metallic atoms are usually overlooked in applications because of their poor performances in magnetic moments and under critical temperatures. Herein, magnetic characteristics of 2D pentagon-based XN (X = B, Al, and Ga) are revealed based on first-principles calculations. It was proven that XN structures are antiferromagnetic semiconductors with bandgaps of 2.
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