Some of the current clinical and biomechanical data suggest that vertebroplasty causes the development of adjacent vertebral fractures shortly after augmentation. These findings have been attributed to high injection volumes as well as high Young's moduli of PMMA bone cements compared to that of the osteoporotic cancellous bone. The aim of this study was to evaluate the use of castor oil as a plasticizer for PMMA bone cements. The Young's modulus, yield strength, maximum polymerization temperature, doughing time, setting time and the complex viscosity curves during curing, were determined. The cytotoxicity of the materials extracts was assessed on cells of an osteoblast-like cell line. The addition of up to 12 wt% castor oil decreased yield strength from 88 to 15 MPa, Young's modulus from 1500 to 446 MPa and maximum polymerization temperature from 41.3 to 25.6°C, without affecting the setting time. However, castor oil seemed to interfere with the polymerization reaction, giving a negative effect on cell viability in a worst-case scenario.
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http://dx.doi.org/10.3233/BME-2012-0679 | DOI Listing |
RSC Adv
January 2025
High-Tech Research and Development Center, Kim Il Sung University Pyongyang Democratic People's Republic of Korea
In this study, we synthesized a water-based, rosin-modified, polymerized oil (WRPO) an addition and polymerization reaction of dehydrated castor oil (DCO), rosin acid (RA), zinc resinate (ZR) and dehydrated castor oil acid (DCOA). Addition and polymerization reactions at 240 °C, followed by neutralization with ammonia, dissolution into butyl alcohol and subsequent dilution with water, were performed at varying DCOA contents of 10%, 20%, 30%, 35% and 40%. WRPO was mixed with butoxymethylmelamine (BMM), a curing agent, at a weight ratio of 80 : 20, and then cured for 2 hours at 130 °C.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore.
A series of biomass-based linear aliphatic polyesters are synthesized by combining sebacic acid (SA) (C10 diacid) and 1,18-octadecanedioic acid (OA) (C18 diacid) with a series of diols with varied alkyl chain lengths (C2 to C10 diols). SA and OA are obtainable from castor oil and palm oil, respectively. The reaction extent (polymerization extent) is high (≥96%) in all cases, and the number-average molecular weight (M) is 10 000-43 000 g mol after purification.
View Article and Find Full Text PDFChemSusChem
January 2025
TU Dortmund University, Department for Biochemical and Chemical Engineering, Laboratory of Industrial Chemistry, Emil-Figge-Straße 66, 44227, Dortmund, Germany.
Platform chemicals from renewable resources with broad applications are highly desirable, particularly for replacing fossil-based monomers. Bifunctional aliphatic ester-aldehydes, accessible via regioselective hydroformylation of unsaturated oleochemicals, can be converted into linear ω-amino/ω-hydroxy esters and dicarboxylic acids-key building blocks for biobased aliphatic polycondensates. However, their success hinges on efficient, economically viable production, with catalyst recycling being critical.
View Article and Find Full Text PDFIn the Rutaceae family is the biggest among all fruits, tradtionally used for several purposes due to its diverse ethnomedicinal, phytochemical, and pharmacological activities. Different portions of this plant have been used as sedatives and anti-inflammatory medications, as well as to treat coughs, fevers, asthma, diarrhea, ulcers, and diabetes. There is a scientific potential for the methanolic seed extract to contain bioactive compounds, similar to those found in other parts of the plant.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
CNBM Zhongyan Technology Co., Ltd., Beijing 100024, China.
This study aims to develop castable polyurethane suitable for applications on wet substrates or underwater construction. Polyurethanes were synthesized using various polyols with similar hydroxyl values, including poly(tetrahydrofuran) polyol, polyester polyol, castor oil-modified polyol, soybean oil-modified polyol, and cashew nut shell oil-modified polyol. The corresponding polyurethane curing products were evaluated for their underwater curing characteristics by volume expansion ratios and adhesion strength on dry and wet substrates, combined with analyses of reaction exothermic behavior, wetting properties on dry and wet substrates, interfacial tension, and microstructure characterization from the perspectives of reaction activity and water solubility.
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