AI Article Synopsis
- The compound N,N-diallyl-4-methyl-1-propyl-2-quinolone-3-carboxamide formed chiral crystals in a P2(1) crystal system through spontaneous crystallization.
- The molecular chirality in these crystals remained intact even after dissolution in a cold solvent.
- This preserved chirality was successfully transferred to new products via a two-step reaction involving hydrogenation followed by intermolecular photocycloaddition.
Article Abstract
N,N-diallyl-4-methyl-1-propyl-2-quinolone-3-carboxamide afforded chiral crystals of a P2(1) crystal system by spontaneous crystallization. The molecular chirality in the crystal was retained after the crystals were dissolved in a solvent at a low temperature, and the frozen molecular chirality was effectively transferred to the products by a two-step reaction involving hydrogenation and intermolecular photocycloaddition reactions.
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