A donor-acceptor dyad model system using a flavin moiety as a photo-active acceptor has been synthesized for an energy and photo-induced electron transfer study. The photophysical investigations of the dyad revealed a multi-path energy and electron transfer process with a very high transfer efficiency. The photo-activity of flavin was believed to play an important role in the process, implying the potential application of flavin as a novel acceptor molecule for photovoltaics.
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http://dx.doi.org/10.1039/c2cp40073a | DOI Listing |
Chem Soc Rev
July 2024
Materials Science and Engineering Program (MSE), Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia.
Over the past decades, the field of organic solar cells (OSCs) has witnessed a significant evolution in materials chemistry, which has resulted in a remarkable enhancement of device performance, achieving efficiencies of over 19%. The photoactive layer materials in OSCs play a crucial role in light absorption, charge generation, transport and stability. To facilitate the scale-up of OSCs, it is imperative to address the photostability of these electron acceptor and donor materials, as their photochemical degradation process remains a challenge during the photo-to-electric conversion.
View Article and Find Full Text PDFAdv Mater
September 2023
Hasselt University, IMOMEC, Wetenschapspark 1, Diepenbeek, 3590, Belgium.
Organic solar cells benefit from non-fullerene acceptors (NFA) due to their high absorption coefficients, tunable frontier energy levels, and optical gaps, as well as their relatively high luminescence quantum efficiencies as compared to fullerenes. Those merits result in high yields of charge generation at a low or negligible energetic offset at the donor/NFA heterojunction, with efficiencies over 19% achieved for single-junction devices. Pushing this value significantly over 20% requires an increase in open-circuit voltage, which is currently still well below the thermodynamic limit.
View Article and Find Full Text PDFInorg Chem
February 2023
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Two cationic zinc(II) complexes with carbazole-type counter-anions, namely, [Zn(tpy)][CAZ--BF] (Zn-) and [Zn(tpy)][CAZ--BF] (Zn-), have been designed and synthesized, where tpy is 2,2':6',2″-terpyridine, CAZ--BF is 4-((9-carbazol-9-yl)phenyl)trifluoroborate, and CAZ--BF is (2-(9-carbazol-9-yl)phenyl)trifluoroborate. The complex cation [Zn(tpy)] (as the acceptor) and the carbazole-type counter-anion CAZ--BF or CAZ--BF (as the donor) form an intracomplex donor/acceptor pair. Single-crystal structures reveal that compared to Zn-, Zn- exhibits a stronger π-π stacking interaction between the carbazole group (as the donor unit) of the counter-anion and the tpy ligand (as the acceptor unit) of [Zn(tpy)] because of the different anchoring position of the BF anion in the counter-anion.
View Article and Find Full Text PDFChem Sci
November 2022
School of Chemistry, Monash University Clayton Victoria 3800 Australia
J Colloid Interface Sci
November 2021
Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang 330096, PR China; Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, PR China. Electronic address:
In this work, we introduced a fullerene acceptor (PCBM) into the binary photo-active layer based on a polymer donor (PM6) and a non-fullerene small molecular acceptor (BTP-BO-4Cl), and as a consequence, the ternary organic solar cells realized a high-power conversion efficiency of 17.39% compared to 16.65% in binary solar cells.
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