A donor-acceptor dyad model system using a flavin moiety as a photo-active acceptor has been synthesized for an energy and photo-induced electron transfer study. The photophysical investigations of the dyad revealed a multi-path energy and electron transfer process with a very high transfer efficiency. The photo-activity of flavin was believed to play an important role in the process, implying the potential application of flavin as a novel acceptor molecule for photovoltaics.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c2cp40073aDOI Listing

Publication Analysis

Top Keywords

photo-active acceptor
8
electron transfer
8
flavin
4
flavin photo-active
4
acceptor efficient
4
efficient energy
4
energy charge
4
transfer
4
charge transfer
4
transfer model
4

Similar Publications

Understanding photochemical degradation mechanisms in photoactive layer materials for organic solar cells.

Chem Soc Rev

July 2024

Materials Science and Engineering Program (MSE), Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia.

Over the past decades, the field of organic solar cells (OSCs) has witnessed a significant evolution in materials chemistry, which has resulted in a remarkable enhancement of device performance, achieving efficiencies of over 19%. The photoactive layer materials in OSCs play a crucial role in light absorption, charge generation, transport and stability. To facilitate the scale-up of OSCs, it is imperative to address the photostability of these electron acceptor and donor materials, as their photochemical degradation process remains a challenge during the photo-to-electric conversion.

View Article and Find Full Text PDF

Organic solar cells benefit from non-fullerene acceptors (NFA) due to their high absorption coefficients, tunable frontier energy levels, and optical gaps, as well as their relatively high luminescence quantum efficiencies as compared to fullerenes. Those merits result in high yields of charge generation at a low or negligible energetic offset at the donor/NFA heterojunction, with efficiencies over 19% achieved for single-junction devices. Pushing this value significantly over 20% requires an increase in open-circuit voltage, which is currently still well below the thermodynamic limit.

View Article and Find Full Text PDF

Cationic Zinc(II) Complexes with Carbazole-Type Counter-Anions: Intracomplex Donor/Acceptor Pairs Affording Exciplexes with Thermally Activated Delayed Fluorescence.

Inorg Chem

February 2023

Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.

Two cationic zinc(II) complexes with carbazole-type counter-anions, namely, [Zn(tpy)][CAZ--BF] (Zn-) and [Zn(tpy)][CAZ--BF] (Zn-), have been designed and synthesized, where tpy is 2,2':6',2″-terpyridine, CAZ--BF is 4-((9-carbazol-9-yl)phenyl)trifluoroborate, and CAZ--BF is (2-(9-carbazol-9-yl)phenyl)trifluoroborate. The complex cation [Zn(tpy)] (as the acceptor) and the carbazole-type counter-anion CAZ--BF or CAZ--BF (as the donor) form an intracomplex donor/acceptor pair. Single-crystal structures reveal that compared to Zn-, Zn- exhibits a stronger π-π stacking interaction between the carbazole group (as the donor unit) of the counter-anion and the tpy ligand (as the acceptor unit) of [Zn(tpy)] because of the different anchoring position of the BF anion in the counter-anion.

View Article and Find Full Text PDF
Article Synopsis
  • - The study involves the self-assembly of a heteropolyoxomolybdate compound and a pyridyl-based diarylethene, resulting in a molecular capsule that is photo-active, specifically designed for efficient light-induced processes.
  • - The arrangement of the diarylethene ligands is influenced by the chemistry of the metal oxide, allowing only a specific form to bond with the polyoxometalate, and the stability of this assembly in solution is confirmed by various spectroscopic methods.
  • - Research reveals a photochemical sequence where light triggers the closing of the diarylethene structure, followed by electron transfer to the polyoxometalate, supported by sophisticated analyses and a setup for measuring quantum yields.
View Article and Find Full Text PDF

Fullerene as an additive for increasing the efficiency of organic solar cells to more than 17.

J Colloid Interface Sci

November 2021

Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang 330096, PR China; Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, PR China. Electronic address:

In this work, we introduced a fullerene acceptor (PCBM) into the binary photo-active layer based on a polymer donor (PM6) and a non-fullerene small molecular acceptor (BTP-BO-4Cl), and as a consequence, the ternary organic solar cells realized a high-power conversion efficiency of 17.39% compared to 16.65% in binary solar cells.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!