Alkylation of [{Ti(η(5)-C(5)Me(5))(μ-NH)}(3)(μ(3)-N)] with MeOTf occurs at the imido ligands to produce the methylamido derivative [Ti(3)(η(5)-C(5)Me(5))(3)(μ(3)-N)(μ-NH)(2)(μ-NHMe)(OTf)] which readily rearranges to form the methylimido complex [Ti(3)(η(5)-C(5)Me(5))(3)(μ(3)-N)(μ-NH)(μ-NH(2))(μ-NMe)(OTf)].
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| http://dx.doi.org/10.1039/c2dt30486d | DOI Listing |
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