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Efficient methods for the direct arylation and deacylative arylation of β-ketophosphonates with iodoarenes in presence of a copper(I) or a copper(II) salt as the catalysts were developed. The corresponding α-arylphosphonates were obtained in high yields. A tentative mechanism for the deacylative arylation reaction was proposed on the basis of the experimental data.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3324819 | PMC |
| http://dx.doi.org/10.1002/adsc.201100605 | DOI Listing |
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