Key developments in NC-AFM have generally involved atomically flat crystalline surfaces. However, many surfaces of technological interest are not atomically flat. We discuss the experimental difficulties in obtaining high-resolution images of rough surfaces, with amorphous SiO(2) as a specific case. We develop a quasi-1-D minimal model for noncontact atomic force microscopy, based on van der Waals interactions between a spherical tip and the surface, explicitly accounting for the corrugated substrate (modeled as a sinusoid). The model results show an attenuation of the topographic contours by ~30% for tip distances within 5 Å of the surface. Results also indicate a deviation from the Hamaker force law for a sphere interacting with a flat surface.
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http://dx.doi.org/10.3762/bjnano.3.26 | DOI Listing |
Anal Chem
December 2024
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China.
Molten salt electrolysis has been widely used in the production and separation of metals, but it still lacks in situ real-time analysis methods to monitor the electrolysis process. In this work, a microplasma spectroscopic real-time analysis (MIPECA) system is developed based on noncontact direct current (DC) glow discharge. With the MIPECA system, the atomic emission spectroscopy of Li and K could be obtained in situ in LiCl-KCl molten salt, and the impact of different operating conditions on spectral signals was investigated.
View Article and Find Full Text PDFSmall
December 2024
School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
Introducing uniform magnetic order in two-dimensional (2D) topological insulators by constructing heterostructures of TI and magnet is a promising way to realize the high-temperature Quantum Anomalous Hall effect. However, the topological properties of 2D materials are susceptible to several factors that make them difficult to maintain, and whether topological interface states (TISs) can exist at magnetic-topological heterostructure interfaces is largely unknown. Here, it is experimentally shown that TISs in a lateral heterostructure of CrTe/Bi(110) are robust against disorder, defects, high magnetic fields (time-reversal symmetry-breaking perturbations), and elevated temperature (77 K).
View Article and Find Full Text PDFJ Phys Chem B
December 2024
Institute of Electronic Structure and Laser, FORTH, Heraklion 70013, Greece.
The response of soft materials to an imposed oscillatory stress is typically frequency dependent, with the most utilized frequency range falling in the range of 10-10 rad/s. In contrast to most conventional contact techniques for measuring material elasticity, like tensile or shear rheology and atomic force microscopy, or invasive techniques using probes, such as microrheology, Brillouin light spectroscopy (BLS) offers an optical, noncontact, label-free, submicron resolution and three-dimensional (3D) mapping approach to access the mechanical moduli at GHz frequencies. Currently, the correlation between the experimental viscoelastic (at lower frequencies) and elastic (at higher frequencies) moduli has fundamental and practical relevance, but remains unclear.
View Article and Find Full Text PDFSci Rep
November 2024
China Institute of Atomic Energy, P. O. Box 275 (26), Beijing, 102413, China.
The cladding of fast reactor fuel rods, made of stainless steel, presents significant challenges in cutting due to its ductility, which leads to increased tool wear and poor cut quality with traditional mechanical methods. Laser cutting has emerged as a superior alternative, offering non-contact precision, high efficiency, and suitability for radioactive environments. This study systematically investigates the effects of laser cutting parameters-cutting speed, focal position, power, and gas pressure-on the cutting quality of simulated fast reactor fuel rods.
View Article and Find Full Text PDFJ Cheminform
November 2024
Departamento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, E-28049, Madrid, Spain.
Non-Contact Atomic Force Microscopy with CO-functionalized metal tips (referred to as HR-AFM) provides access to the internal structure of individual molecules adsorbed on a surface with totally unprecedented resolution. Previous works have shown that deep learning (DL) models can retrieve the chemical and structural information encoded in a 3D stack of constant-height HR-AFM images, leading to molecular identification. In this work, we overcome their limitations by using a well-established description of the molecular structure in terms of topological fingerprints, the 1024-bit Extended Connectivity Chemical Fingerprints of radius 2 (ECFP4), that were developed for substructure and similarity searching.
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