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Metal ion redox potential plays an important role in high-yield synthesis of monodisperse silver nanoparticles. | LitMetric

Metal ion redox potential plays an important role in high-yield synthesis of monodisperse silver nanoparticles.

Chem Commun (Camb)

Division of Nanobiomedicine and i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China.

Published: May 2012

AI Article Synopsis

  • A new and simple method is created to produce silver nanoparticles that are all the same size and in larger quantities by adding a tiny amount of Fe(3+) ions during the reaction of AgNO(3) with oleic acid and oleylamine.
  • The process suggests that Fe(2+) ions help speed up the formation and growth of these nanoparticles by facilitating electron transfer between Ag(+) and Fe(2+).
  • The Fe(2+) ions are generated when oleylamine reduces Fe(3+) ions during the reaction.

Article Abstract

A facile method is developed to prepare monodisperse silver nanoparticles in a much enhanced yield by adding a trace amount of Fe(3+) ions into the reaction of AgNO(3) with oleic acid and oleylamine. We propose that Fe(2+) ions speed up the nucleation and growth of silver nanoparticles due to the electron-transfer between Ag(+) and Fe(2+), in which Fe(2+) is from Fe(3+) reduced by oleylamine.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c2cc18152eDOI Listing

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