Graphene was synthesized by chemical vapor deposition using polystyrene as the solid carbon source. The number of graphene layers could be controlled by regulating the weight of polystyrene under atmospheric pressure at 1000 °C. Silver nanoparticles were then deposited on the graphene by a citrate reduction method. The interaction between graphene and silver was investigated by suface-enhanced Raman scattering spectra and X-ray photoelectron spectroscopy. The change in the G band position indicates n-type doping of the graphene due to an interaction between the silver and the graphene. Silver interlayer doped four-layer graphene shows a sheet resistance of 63 Ω/sq and a light transmittance of 85.4% at 550 nm. The optical and electrical quality of graphene exceeds the minimum industry standard for indium tin oxide replacement materials. It is clearly understood that the environmental sheet resistance stability of the interlayer doped graphene film is better than that of surface doped graphene sheets. The presence of graphene at the surface also acts as a protective layer for the inner silver ions and clusters.
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January 2025
School of Chemistry, South China Normal University, Guangzhou, 510006, P. R. China.
Intrinsic low conductivity, poor structural stability, and narrow interlayer spacing limit the development of MnO in sodium-ion (Na) supercapacitors. This work constructs the hollow cubic Mn-PBA precursor through an ion-exchange process to in situ obtain a hollow cubic H-Ni-MnO composite with Ni doping and oxygen vacancies (O) via a self-oxidation strategy. Experiments and theoretical calculations show that the hollow nanostructure and the expanding interlayer spacing induced by Ni doping are beneficial for exposing more reactive sites, synergistically manipulating the Na transport pathways.
View Article and Find Full Text PDFNat Commun
December 2024
Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian, China.
Highly efficient perovskite solar cells (PSCs) in the n-i-p structure have demonstrated limited operational lifetimes, primarily due to the layer-to-layer ion diffusion in the perovskite/doped hole-transport layer (HTL) heterojunction, leading to conductivity drop in HTL and component loss in perovskite. Herein, we introduce an ultrathin (~7 nm) p-type polymeric interlayer (D18) with excellent ion-blocking ability between perovskite and HTL to address these issues. The ultrathin D18 interlayer effectively inhibits the layer-to-layer diffusion of lithium, methylammonium, formamidium, and iodide ions.
View Article and Find Full Text PDFAdv Mater
December 2024
Division of Advanced Materials, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, 215123, China.
Semiconducting single-wall carbon nanotubes (s-SWCNTs) represent one of the most promising materials for surpassing Moore's Law and developing the next generation of electronic devices. Despite numerous developed approaches, reducing the contact resistance of s-SWCNTs networks remains a significant challenge in achieving further enhancements in electronic performance. In this study, antimony triiodide (SbI) is efficiently encapsulated within high-purity s-SWCNTs films at low temperatures, forming 1D SbI@s-SWCNTs vdW heterostructures.
View Article and Find Full Text PDFRSC Adv
December 2024
Department of Physics, College of Science, University of Bisha P.O. Box 551 Bisha 61922 Saudi Arabia.
Iron-doped tungsten disulfide (Fe-WS) nanoparticles were synthesized a green method using neem leaf extract. X-ray diffraction (XRD) confirmed structural changes, with the formation of a hexagonal structure. The -spacing is increased by Fe doping (6.
View Article and Find Full Text PDFNanoscale
December 2024
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China.
The high overpotential of the oxygen evolution reaction (OER) and the strong corrosion of the anode are the main problems currently faced by the zinc hydrometallurgical process. This study achieved the successful synthesis of titanium dioxide nanotubes doped by Al and V on a TC4 alloy. Subsequently, a composite electrode, TC4/AVTN-7/PbO-ZrO-CoO, was prepared utilizing composite electrodeposition.
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