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Chlorine-induced assembly of a cationic coordination cage with a μ5-carbonato-bridged Mn(II)24 core. | LitMetric
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Chlorine-induced assembly of a cationic coordination cage with a μ5-carbonato-bridged Mn(II)24 core.

Ke-Cai Xiong Fei-Long Jiang Yan-Li Gai Da-Qiang Yuan Dong Han Jie Ma Shu-Quan Zhang Mao-Chun Hong

Chemistry

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, PR China.

Published: April 2012

Chlorine caged in! The chlorine-induced assembly of six shuttlecock-like tetranuclear Mn(II) building blocks generated in situ based on p-tert-butylthiacalix[4]arene and facial anions gave rise to a novel truncated distorted octahedral cationic coordination cage with a μ(5)-carbonato-bridged Mn(II)(24) core.

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http://dx.doi.org/10.1002/chem.201200125DOI Listing

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