Straightforward glycosylation of alcohols and amino acids mediated by ionic liquid.

Carbohydr Res

University of Cergy-Pontoise, Laboratoire de Synthèse Organique Sélective et Chimie bioOrganique, Neuville-sur-Oise, F-95031 Cergy-Pontoise, France.

Published: May 2012

Green glycosylation of functionalized alcohols and α-amino acids, using an ionic liquid as a recyclable solvent, was performed in one step directly from the unprotected monosaccharide under scandium triflate or ferric chloride catalysis. Pure α- and β-glycosides could be obtained after specific enzymatic hydrolysis.

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http://dx.doi.org/10.1016/j.carres.2012.03.004DOI Listing

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