Rational design of a NIR-emitting Pd(II) sensor via oxidative cyclization to form a benzoxazole ring.

Chem Commun (Camb)

Department of Chemistry & Maurice Morton Institute of Polymer Science, The University of Akron, Akron, OH 44325, USA.

Published: April 2012

By using the substituent effect to tune the palladium(II)-involved reactivity, a new probe is found to respond quantitatively to Pd(II). Unexpectedly, the probe gave an emission band in the desirable near-infrared (NIR) region (780 nm), thus providing the first NIR sensor for palladium detection.

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Source
http://dx.doi.org/10.1039/c2cc30240cDOI Listing

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