A stopped-flow method is used to study the effects of water and reactant acid anion TB(-) = tetrakis(pentafluorophenyl)borate on the homogeneous oxygen reduction catalyzed by the protonated tetraphenylporphyrin. Observed competitive inhibition of the catalyst is linked to the DFT free energy of extraction of O(2), water, and TB(-) from the porphyrin complex.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2cc31082a | DOI Listing |
Publication Analysis
Top Keywords
competitive inhibition
8
inhibition metal-free
4
metal-free porphyrin
4
porphyrin oxygen-reduction
4
oxygen-reduction catalyst
4
catalyst water
4
water stopped-flow
4
stopped-flow method
4
method study
4
study effects
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!