Batteries have powered vehicles for more than a century, but recent advances, especially in lithium-ion (Li-ion) batteries, are bringing a new generation of electric-powered vehicles to the market. Key barriers to progress include system cost and lifetime, and derive from the difficulty of making a high-energy, high-power, and reversible electrochemical system. Indeed, although humans produce many mechanical and electrical systems, the number of reversible electrochemical systems is very limited. System costs may be brought down by using cathode materials less expensive than those presently employed (e.g., sulfur or air), but reversibility will remain a key challenge. Continued improvements in the ability to synthesize and characterize materials at desired length scales, as well as to use computations to predict new structures and their properties, are facilitating the development of a better understanding and improved systems. Battery research is a fascinating area for development as well as a key enabler for future technologies, including advanced transportation systems with minimal environmental impact.
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http://dx.doi.org/10.1146/annurev-chembioeng-073009-100942 | DOI Listing |
Adv Mater
January 2025
Materials Science and Engineering Program, Walker Department of Mechanical Engineering and Texas Materials Institute, The University of Texas at Austin, Austin, TX, 78712, USA.
Anode-free all solid-state batteries (AF-ASSBs) employ "empty" current collector with three active interfaces that determine electrochemical stability; lithium metal - Solid electrolyte (SE) interphase (SEI-1), lithium - current collector interface, and collector - SE interphase (SEI-2). Argyrodite LiPSCl (LPSCl) solid electrolyte (SE) displays SEI-2 containing copper sulfides, formed even at open circuit. Bilayer of 140 nm magnesium/30 nm tungsten (Mg/W-Cu) controls the three interfaces and allows for state-of-the-art electrochemical performance in half-cells and fullcells.
View Article and Find Full Text PDFDalton Trans
January 2025
School of Physics and Optoelectronics, South China University of Technology, Guangzhou 510640, P. R. China.
CaCoO/rGO was prepared by combining a sol-gel strategy and mechanical ball milling method. The Rietveld refinement results demonstrated a single-phase structure with a monoclinic symmetry. When utilized as an anode for lithium-ion batteries, it exhibited excellent rate performance and electrochemical stability due to the significantly decreasing particle size as well as the formation of a conductive rGO network in the composite after ball milling.
View Article and Find Full Text PDFHeliyon
December 2024
Department of Chemical, Biological & Battery Engineering, Gachon University, Seongnam-si, Gyeonggi-do, 13120, Republic of Korea.
In this study, shell-derived cellulose was successfully produced, and the hydrothermal method was employed to generate ZnO@C (ZOC) composites, which were then subjected to calcination in N gas at a temperature of 600 °C for varying durations. X-ray diffraction and thermogravimetric analyses demonstrated that the annealing duration had a substantial impact on the quantities of C and ZnO in the ZOC composites. The scanning electron microscope images indicated the presence of ZnO nanoparticles on the surface of the C phase and revealed a similar morphology among the ZOC composites.
View Article and Find Full Text PDFHeliyon
December 2024
Radiation Fusion Research Division, Advanced Radiation Technology Institute (ARTI), Korea Atomic Energy Research Institute (KAERI), 29 Geumgu-gil, Jeongeup-si, Jeollabuk-do, 56212, Republic of Korea.
Electrode material capacities and cycle performances must improve for large-scale applications such as energy storage systems. Numerous investigations have developed cathode materials to improve lithium-ion batteries (LIBs) performance: however, few have examined new anode materials. In this study, we synthesized a Ni-B/reduced graphene oxide (RGO) composites via a simple chemical reaction method to enhance the stability of electrodes in LIBs.
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December 2024
Department of Physics, School of Advanced Sciences, Vellore Institute of Technology (VIT) Chennai, Vandalur - Kelambakkam Road, Chennai 600127, India.
Nickel pyrovanadate (NVO) and compositing rGO in different concentrations with NVO are synthesized via the solvothermal process. XRD patterns reveal the formation of crystalline NVO and amorphous rGO in the nanocomposite. The morphology of the material resembles the formation of an NVO hollow nanosphere through a template-free synthesis route with the effect of ethylene glycol.
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