We report a highly efficient cryo-cooled eye-safe laser operation of a resonantly-pumped (in-band) Er³⁺:GdVO₄ single crystal. The maximum continuous wave (CW) power of 10.3 W with 84% slope efficiency was achieved at 1598.7 with pumping at 1538.6 nm by a spectrally-narrowed Er-fiber laser. Under the 1529 nm resonant pumping by a commercially available diode bar stack operating in a quasi-CW (QCW) mode, the laser delivered 37 W of output power with 68% slope efficiency. This is believed to be the first reported cryo-cooled Er³⁺:GdVO₄ laser, resonantly-pumped into the ⁴I₁₅/₂ →⁴I₁₃/₂ transition.
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http://dx.doi.org/10.1364/OE.20.006080 | DOI Listing |
Acta Crystallogr D Struct Biol
August 2024
Swiss Light Source, Center for Photon Science, Paul Scherrer Institute, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland.
Advances in structural biology have relied heavily on synchrotron cryo-crystallography and cryogenic electron microscopy to elucidate biological processes and for drug discovery. However, disparities between cryogenic and room-temperature (RT) crystal structures pose challenges. Here, Cryo2RT, a high-throughput RT data-collection method from cryo-cooled crystals that leverages the cryo-crystallography workflow, is introduced.
View Article and Find Full Text PDFJ Am Chem Soc
May 2024
Gas Phase Chemical Physics, Sandia National Laboratories, Livermore, California 94550, United States.
We present a detailed study of the time-dependent photophysics and photochemistry of a known conformation of the two protonated pentapeptides Leu-enkephalin (Tyrosine-Glycine-Glycine-Phenylalanine-Leucine, YGGFL) and its chromophore-swapped analogue FGGYL, carried out under cryo-cooled conditions in the gas phase. Using ultraviolet-infrared (UV-IR) double resonance, we record excited state IR spectra as a function of time delay between UV and IR pulses. We identify unique Tyr OH stretch transitions due to the S state and the vibrationally excited triplet state(s) formed by intersystem crossing, T(v).
View Article and Find Full Text PDFJ Synchrotron Radiat
May 2024
Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE, United Kingdom.
Maximizing the performance of crystal monochromators is a key aspect in the design of beamline optics for diffraction-limited synchrotron sources. Temperature and deformation of cryo-cooled crystals, illuminated by high-power beams of X-rays, can be estimated with a purely analytical model. The analysis is based on the thermal properties of cryo-cooled silicon crystals and the cooling geometry.
View Article and Find Full Text PDFJ Synchrotron Radiat
March 2024
Synchrotron Radiation Facility, Institute of Advanced Science Facilities, Guangming, Shenzhen, Guangdong 518107, People's Republic of China.
A method to optimize the thermal deformation of an indirectly cryo-cooled silicon crystal monochromator exposed to intense X-rays at a low-emittance diffraction-limited synchrotron radiation source is presented. The thermal-induced slope error of the monochromator crystal has been studied as a function of heat transfer efficiency, crystal temperature distribution and beam footprint size. A partial cooling method is proposed, which flattens the crystal surface profile within the beam footprint by modifying the cooling contact area to optimize the crystal peak temperature.
View Article and Find Full Text PDFJ Phys Chem A
August 2023
Gas Phase Chemical Physics, Sandia National Laboratories, Livermore, California 94550, United States.
UV photofragment spectroscopy and IR-UV double resonance methods are used to determine the structure and spectroscopic responses of a three-dimensional [2.2.2]-benzocryptand cage to the incorporation of a single K or Ba imbedded inside it (labeled as K-BzCrypt, Ba-BzCrypt).
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