μ-4,4'-Bipyridine-bis-[aqua-(4-hy-droxy-pyridine-2,6-dicarboxyl-ato)copper(II)].

Acta Crystallogr Sect E Struct Rep Online

Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, People's Republic of China.

Published: March 2012

The title compound, [Cu(2)(C(7)H(3)NO(5))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a centrosymmetric binuclear molecule. Each completely deprotonated 4-hy-droxy-pyridine-2,6-dicarb-oxy-lic acid mol-ecule assumes a tridentate chelating coordination mode. The square-pyramidal coordination geometry around the Cu(II) ion is completed by the bridging bipyridine ligand and an apical water molecule. Adjacent complexes are connected via O-H⋯O and C-H⋯O hydrogen bonds to generate a three-dimensional supra-molecular structure.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297272PMC
http://dx.doi.org/10.1107/S1600536812004758DOI Listing

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