In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol-ecules are linked by weak C-H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π-π stacking inter-actions between the aromatic rings [shortest centroid-centroid distance = 3.758 (4) Å].
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297231 | PMC |
| http://dx.doi.org/10.1107/S160053681200342X | DOI Listing |
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cis-Dichloridobis[tris-(2-methyl-phen-oxy)phosphane-κP]palladium(II).
Acta Crystallogr Sect E Struct Rep Online
March 2012
Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie, 50-383 Wrocław, Poland.
In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol-ecules are linked by weak C-H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π-π stacking inter-actions between the aromatic rings [shortest centroid-centroid distance = 3.
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