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catena-Poly[[bis-(dimethyl-formamide-κO)cadmium]-bis-(μ-4-nitro-phenyl-cyanamido-κN:N)]. | LitMetric

In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa-hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl-formamide mol-ecules occupy the axial positions. The anions act as bridging ligands, connecting the Cd atoms into a one-dimensional coordination polymer along [100].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297207PMC
http://dx.doi.org/10.1107/S1600536812001924DOI Listing

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